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Organometallic Radicals
A 19-electron organometallic radical was produced by the reaction of muonium with ferrocene and characterized by avoided level crossing muon spin resonance (ALC-muSR) and... -
Nonmonotonic phase diagrams in molecular magnets
We propose longitudinal field muSR on a 2D molecular magnetic system which has been suggested to have an unusual B-T phase diagram. Our goal is to probe the transition from... -
Field-induced Tomonaga-Luttinger Liquid phase in a spin ladder
The new molecular magnet bis(2,3-dimethylpyridinium) tetrabromocuprate (DIMPY) is a strong-leg spin ladder with a quantum critical point at 3 T separating a low-field... -
The electronic structure and magnetic properties of metal nanoparticles stabi...
In recent years, nanoparticles have been a major source of interest in a wide range of fields. Our long term objectives are tuning the free radical reactivity on the surface of... -
Copy of: Spin Dynamics of the Central Fe Atom of Reduced Model Fe-Porphyrins
We propose to study the dynamics of the central Fe spin in reduced model Fe-porphyrins. Our aim is to clarify a relatioship between the spin dynamics of Fe and functions of... -
muSR in the presence of significant spin-orbit coupling
The great majority of known muonium defect centres and muonium substituted organic radicals have essentially spin-only magnetism, with few exhibiting any noticeable departure... -
The effect of metal nanoparticles on the electronic structure of bound free r...
In recent years, the noble metals nanoparticles (MNPs) have been the subject of intense interest in areas of materials science, biotechnology, medicine and organic chemistry for... -
End-Game: Cornering Solvent Effects on H-Addition in Green Tea Anti-Oxidants
Our ongoing project to characterise radical scavenging by the green tea anti-oxidant EGCG and its D-ring analogue, (3,4,5-(OH)3-Bz) is near-complete. ALC-MuSR experiments on the... -
Level crossings in the open ring molecular magnet Cr8Cd
Molecular nanomagnets (MNMs) comprise clusters of exchange coupled transition metal ions which often have a negative anisotropy constant, favoring a ground state with a large... -
Separating static and dynamic contributions to the muon relaxation in Ca3(Co,...
Ca3CoMnO6 has alternating ions in ferromagnetic Ising chains that are antiferromagnetically coupled on a triangular lattice and realizes an important model in frustrated... -
Study on the dynamical spin equilibrium of (n-C2H5)4N[ZnIIFeIII(C2O3S)3] unde...
The main purpose of this proposed experiment is to investigate the time scale of the dynamical spin equilibrium for the iron(III) site in (n-C2H5)4N[ZnIIFeIII(mto)3] (mto =... -
Field induced spin Luttinger liquid phase in a spin ladder
Spin ladders present a class of low-dimensional quantum magnets that occupy a regime of rather subtle behavior which lies between the stark extremes of a one-dimensional chain... -
Models of the [FeFe]-hydrogenase active site: raising the symmetry
The [FeFe]-hydrogenase enzymes are some of the best catalysts know for generating hydrogen. We have an ongoing programme to understand how their chemistry works, and to... -
Spin Dynamics in Organic-Inorganie Hybrid Systems
The organic-inorganic hybrid systems consist of organic and inorganic components forming a 2 D layered structure. The distance between adjacent magnetic layers is quite far,... -
Probing the [FeFe]-hydrogenase subsite using muon spectroscopy
Previous ALC measurements of the Fe2(pdt)(CO)4(PMe3)2 and [Fe2(pdt)(CO)4(CN)2]2- (referred to as 1 and 2) model hydrogenase subsites have yielded some intriguing results (RB... -
Probing the [FeFe]-hydrogenase using muon spectroscopy
During our previous experiment on HiFi (RB1320541) we measured the ALC spectrum of the Fe2(µ-pdt)(CO)4(PMe3)2 model hydrogenase complex over multiple temperatures. The spectra... -
Probing the spin dynamics in the pseudo-quaternary Y1-xErxNi2B2C compounds
Our uSR measurements on superconducting Y1-xErxNi2B2C shows a slowing of the Er spin dynamics upon cooling to 2.5 K, but the depolarisation rate does not critically diverge and...
