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The topotactic reduction and anion exchange of complex oxy-halides
The reaction of LiH with the oxy-chloride Sr3Fe2O5Cl2 initially leads to the topotactic deintercalation of oxide ions and the formation of Sr3Fe2O4Cl2 containing sheets of... -
Topochemically Reduced Vanadium oxides
Recently we have been investigating low-temperature synthesis routes to prepare novel complex transition metal oxide phases with highly unusual oxidation states and/or... -
Topotactically reduced phases containing square planar Co(II) centres
The topotactic reduction of Sr3Co2O5Cl2 and Sr3Co2O5.80 yields the Co(II) phases Sr3Co2O4Cl2 and Sr3Co2O5 respectively. These phases contain corner linked arrays of...
