21 datasets found

Apatites are a large group of chemically and structurally flexible functional materials with important applications as solid electrolytes. The majority of known apatite...

We have developed and demonstrated a novel process to overcome chemical reaction equilibrium constraints on an important reversible industrial chemical reaction by using...

We seek to develop new MOFs for sensing and removal of toxic gases (e.g., SO2) and request 4 days on POLARIS to study the structural binding details and dielectric data...

BiFeO3 is by far the most widely studied multiferroic material and yet many mysteries remain in the phase diagram. One mystery is the crystal structure of the high T gamma...

We ask for 3 days on GEM to study in-situ the decomposition of the Na-substituted LiNH2 phases, Li1-xNaxND2, LiNa2(ND2)3, Li3Na(ND2)4 and their reactions with LiD. LiNH2 is the...

We propose to use the HRPD to establish the sequence of structures, and the nature of the transitions between these, in two complex manganites Sr0.5Pr0.5MnO3 and...

The physical properties of the perovskite family remain an enduring topic in solid state research. In this proposal we aim to study the solid state structural phase transitions...

Ammonia has been proposed as a high density chemical energy-storage media, which can be safely and reversible stored within low cost saline halides. Here we propose to extend...

Light metal amides and imides are a new class of highly active ammonia decomposition catalysts. Indeed, composites of lithium imide and transition metal nitrides are likely to...

This proposal seeks to study three systems associated with heat-storage applications using in situ neutron powder diffraction. The first experiment will focus on a sample of...

Recently [RB 900007], we have demonstrated that it is possible to determine the detailed site-by-site behaviour of hydrogen during in-situ absorption and desorption in metal...

We request 3 days on POLARIS to study the detailed crystal structure of a sodium battery cathode material that is currently under consideration for use in commercial sodium...

Geometric ferroelectrics are an unusual and rare class of materials which exhibit spontaneous electrical polarisation due purely to 'geometric' effects, i.e. caused by atomic...

The development of more active catalysts for the production of ammonia will have a worldwide impact on the energy cost of producing fertiliser. Composites of lithium hydride and...

It is generally accepted that austenitic steels (fcc) show no ferromagnetic signature. However, thermomagnetic measurements suggest an unexpected ferromagnetic transition (Tc =...

We have recently discovered that light metal amides and imides are excellent cattalysts for the decomposition of ammonia. We request 3 days on POLARIS to perform in situ neutron...

Bismuth ferrite, BiFeO3, is a much-studied ceramic showing both dielectric and magnetic ordering at relatively high temperatures. In order to improve its properties there has...

Among light metal amide-imide catalysts for ammonia decomposition, lithium-calcium imide is the most promising candidate for practical application. Ex situ diffraction data...

Sr3Ru2O7 is a layered Ruddlesden-Popper perovskite which displays intriguing behaviour at low temperatures and high magnetic field. It can be tuned close to a quantum critical...

NiSi is a technologically important material that is also of interest to Earth Scientists because of the possible role of Ni and Si in the Earth¿s core. It crystallises in the...