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Structural investigation of nano sized CeO2 and ZnO systems
We will investigate bulk and nano size ceria and zinc oxide prepared by solvothermal methods to determine the defect chemistry associated with these solids. We will use neutron... -
Characterising new high-pressure phases of ammonia monohydrate
Over the past two years I have carried out high-pressure surveys of the ammonia monohydrate (AMH) phase diagram using a Paris-Edinburgh press mounted on the D20 beam-line at the... -
Transformations in B2O3 glass under pressure
B2O3 is a prototypical glass forming oxide material and is an essential component in many industrial glasses. Unlike SiO2 and GeO2 its structure under ambient conditions is not... -
Polyamorphism in Glassy GeO2
The object of this proposal is to determine, by using neutron diffraction, the nature of the polyamorphic phase transition that occurs in glassy GeO2 with increasing pressure.... -
Pressure-induced changes in intermediate range order in the candidate polyamo...
This proposal is a continued exploration of the non-recoverable changes that have been reported in the structure of vitreous SiO2 when compressed. This proposed experiment will... -
Mechanism of network collapse in strong network glass forming systems
The object of this proposal is to investigate the mechanism of network collapse in the ¿strong¿ network glass forming system GeO2 in the pressure range between 9 and 16 GPa... -
Insulator to metal transition in TiOCl at high pressures
We propose to study the high temperature structure of TiOCl where a pressure induced metal to insulator transition has been reported recently by Kuntscher et al.Due to our...
