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High temperature neutron powder diffraction studies of polymorphism in Li3+xV...
Novel oxide ceramics with high values of lithium-ion conductivity at ambient temperatures are required as an essential part of the development of new lithium battery... -
Probing bulk heterojunction (BHJ) thin films with graded morphologies using SANS
This projects aims to contribute to a better understanding of the relationship between processing conditions, active layer morphology and device performance in polymer solar... -
Establishing H atom positions and H-bonding patterns in Zn5(OH)10 x 2H2O
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Dr
Li-enriched layered transition metal cathode materials are attracting long-standing interest since they exhibit energy densities and capacities significantly higher than the... -
Simltaneous dielectric spectroscopy and neutron diffraction
We have constructed a novel microwave frequency resonator that can sit within the GEM and POLARIS diffractometers and will allow us to simultaneously collect diffraction and... -
Structure Direction from Electrons in the Presence of the 'Alkalide Option': ...
We request 5 days on SANDALS to investigate the structural effect of expanded metals in the LiNa-MeNH2 system at three different concentrations. The interplay between... -
An in situ study of structural and magnetic order in LaSrCoFeO6-x
LaSrCoFeO6 is a rhombohedral perovskite, and can be reduced to the orthorhombic brownmillerite LaSrCoFeO5 in reducing atmospheres at around 600 deg C. This material is air... -
Determination of the bondlength of the surface hydride in PdH
Supported palladium particles are used as catalysts in many processes. In the course of investigation of Pd-based catalysts used for the selective hydrogenation of nitro-arenes... -
How Encapsulated is a Sodide? Li+Na--EtNH2 vs Li+e--EtNH2
We have recently begun to look at how large, polarisable alkalides (group 1 metal anions) are solvated in solution. This proposal aims to determine how ethylamine is able to... -
New Ruthenium-based dyes for environmentally friendly optical devices
The cis-[Ru(bipy)2(PTA)2]Cl2, trans-[Ru(bipy)2(PTA)2]OTf2 ruthenium complexes are highly water soluble and luminescent in water at room temperature. Additionally, their optical... -
Investigation of cement pore structure evolution in underground repository co...
It is proposed that radioactive waste generated in the Netherlands be buried underground in Boom clay formations. As this will need to be stored for hundreds of thousands of... -
RF μSR in the gas phase: understanding a ¿null¿ result
We have made a significant effort to develop Radio Frequency μSR (RF μSR) as a technique for spectroscopy of organic radicals in the gas phase. Realising this method... -
Total Scattering Study of Hexagonal and Rhombohedral Bi2O3 Based Electrolytes
Bismuth oxide based electrolytes have been widely studied due to their high oxide ion conductivity. The d-phase of Bi2O3 shows the highest known oxide-ion conductivity of any... -
Characterization of heterogeneous solvent structure in a carbon capture fluid
We propose to use neutron scattering experiments to gain molecular level insight into an intriguing liquid structure observed in a water-free CO2-capture solvent. Switchable... -
Neutron total scattering investigation of Pr2NiO4+d heated under O2 flow
This application is concerned with the defect chemistry and stability of Pr2NiO4+d, a highly disordered energy material whose crystal structure is still subject to controversy.... -
Blue sample, in vacuum, 15x20mm
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Structural Changes through the Semiconductor to Metal Transition in Cu2ZnGeSe4
We wish to collect powder neutron diffraction data as a function of temperature to investigate structural changes through a phase transition in the parent thermoelectric phase... -
Development of a Novel Low - Intermediate Temperature Solid Proton Conductor
The compound, Si5O(PO4)6, is a component of a solid phosphoric acid catalyst, it has highly unusual coordination of the silicon (octahedral, as well as the more common... -
Programme Access Rosseinsky
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Kinetics and growth mode of aggregation phenomena inside polymer brushes
We will use time-resolved specular neutron reflectivity measurements to follow the in-situ growth of polymer brushes by surface-initiated ATRP. This will enable us to determine...