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Neutron diffraction studies of nano-diamond particles
Nano-diamond particles are synthesised by detonation of TNT and Hexogen, resulting in a shockwave which produces diamond nanoparticles with an average size of around 5 nm,... -
Simultaneous Microwave Dielectric Spectroscopy and Neutron Diffraction to Mon...
With appropriate storage materials, ammonia has great potential as a fuel. We propose to use a novel piece of equipment, which combines microwave and neutron diffraction... -
Investigating reversible heterolytic H2 activation in Frustrated Lewis Acid B...
Remarkably, hydrogen may be activated for chemical reaction at room temperature using a new family of frustrated Lewis acid-base pair (FLB) materials. In these complexes... -
Characterization of heterogeneous solvent structure in a carbon capture fluid
We propose to use neutron scattering experiments to gain molecular level insight into an intriguing liquid structure observed in a water-free CO2-capture solvent. Switchable... -
In-situ hydrogen decomposition studies of ammonia borane and the diammoniate ...
Ammonia borane (AB) is one of the most promising hydrogen storage materials. We have extensively studied the low temperature behaviour of this material This proposal asks for 3... -
The Interaction of Ammonia with Binary and Ternary Nitrides
We request 2 days on GEM in conjunction with the IGAn apparatus to investigate the formation of lithium amide (LiNH2) from the interaction of Li3N with ammonia (ND3), and the... -
In situ studies on hydride diffusion and exchange in alkaline earth hydrides ...
Thermogravimetric analysis on alkaline earth hydrides in St Andrews has revealed a remarkably fast exchange of deuterium and hydrogen by alkaline earth hydrides at relatively... -
Further studies of the ethanol-to-gasoline reaction
In our recent beamtime (RB 1820043 TOSCA and RB 1820044 MAPS), we prepared a series of ZSM5 samples that had undergone the ethanol-to-gasoline (ETG) reaction for different times... -
In situ studies on hydride diffusion and exchange in alkaline earth hydrides ...
Thermogravimetric analysis on alkaline earth hydrides in St Andrews has revealed a remarkably fast exchange of deuterium and hydrogen by alkaline earth hydrides at relatively... -
Study of NH4+ mobility in ammonia borane, ammonium borohydride and methyl amm...
We request 5 days on EMU to study the NH4+ ion mobility in the light borohydride materials NH3BH3, NH4BH4 and CH3NH3BH4. As has been proposed by Stowe et al., during the... -
In situ studies on the decomposition of NaNH2 and possible formation of Na2NH.
Group 1 amides of general formula MNH2 are some of the most promising materials for hydrogen storage applications due to their relatively low temperatures of hydrogen evolution... -
IN-SITU NEUTRON DIFFRACTION STUDIES OF METAL-HYDRIDE HYDROGEN STORAGE MATERIALS
Hydrogen storage is considered to be one of the principal technological barriers in the transition towards a hydrogen-based economy. In this proposal, we plan to look at the key... -
MAPS Investigation of the decompositon of LiNH2BH3
Ammonia borane, NH3BH3, has been extensively studied as a potential hydrogen storage material because of its high hydrogen content (19.6wt%) and relatively low decomposition... -
Combined in-situ structural and hydrogen desorption/absorption studies of hyd...
The Li?N?H hydrogen storage system is one of the most promising candidates for hydrogen storage in vehicular applications and the addition of halide ions significantly increases... -
Single Crystal Investigations of Polymorphism and Disorder in CH3NH3PbI3
Photovoltaics are one of the most promising technologies for meeting future energy requirements. CH3NH3PbI3 was first used in a solar cell in 2009, which gave an efficiency of... -
A PDF investigation of synthetic Georgite - a new, high activity catalyst
Synthetic Georgite has shown high catalytic activity for a number of catalytic processes including methanol synthesis and the water gas shift reaction. Consequently, it is of... -
Neutron reflectivity investigation of hydrogen in barrier oxide-coated Duplex...
The need for structural materials that can resist hydrogen assisted degradation becomes critical for the continuation of the development of the hydrogen economy. Hydrogen... -
Temperature-dependent molecular orientation distribution function analysis of...
Ammonia is an extremely important industrial chemical and a fundamental canonical hydrogen-bonded solid. An accurate and precise crystal structure for solid ammonia at ambient... -
In-situ Battery Discharge Studies of Thermal Batteries using Transition Metal...
Thermal batteries find use in applications such as emergency power systems and ejector seats in aircraft. They operate at elevated temperatures of around 400-500 °C, where the...