Triple ^13^C-substituted ethyl cyanide

DOI

A recently published astronomical detection of all three doubly ^13^C-substituted ethyl cyanides toward Sgr B2(N2) motivated us to investigate triple ^13^C isotopic species that are expected to be also present in the ISM. We aim to present an experimental study of the rotational spectrum of triple ^13^C-substituted ethyl cyanide, ^13^CH_3_ ^13^CH_2_ ^13^CN, in the frequency range 150-990GHz. We want to use the determined spectroscopic parameters for searching for ^13^CH_3_ ^13^CH_2_ ^13^CN in ALMA data. The main objective of this work is to provide accurate frequency predictions to search for this molecule in the Galactic center source Sagittarius B2(N) and to facilitate its detection in space. The laboratory rotational spectrum of ^13^CH_3_ ^13^CH_2_ ^13^CN has been recorded with the Lille's fast DDS solid-state spectrometer between 150GHz and 990GHz. Results. More than 4000 rotational transitions were identified in the laboratory. The quantum numbers reach J=115 and Ka=39. Watson's Hamiltonian in the A and S reductions were used to analyze the spectra. Accurate spectroscopic parameters were determined. The rotational spectra of the ^13^C containing species CH3CH2CN have been assigned, thus allowing the determination of the rotational and centrifugal distortion constants.

Identifier
DOI http://doi.org/10.26093/cds/vizier.36010002
Source https://dc.g-vo.org/rr/q/lp/custom/CDS.VizieR/J/A+A/601/A2
Related Identifier https://cdsarc.cds.unistra.fr/viz-bin/cat/J/A+A/601/A2
Related Identifier http://vizier.cds.unistra.fr/viz-bin/VizieR-2?-source=J/A+A/601/A2
Metadata Access http://dc.g-vo.org/rr/q/pmh/pubreg.xml?verb=GetRecord&metadataPrefix=oai_b2find&identifier=ivo://CDS.VizieR/J/A+A/601/A2
Provenance
Creator Pienkina A.O.; Margules L.; Motiyenko R.A.; Mueller H.S.P.; Guillemin J.-C.
Publisher CDS
Publication Year 2017
Rights https://cds.unistra.fr/vizier-org/licences_vizier.html
OpenAccess true
Contact CDS support team <cds-question(at)unistra.fr>
Representation
Resource Type Dataset; AstroObjects
Discipline Astrophysics and Astronomy; Interdisciplinary Astronomy; Natural Sciences; Physics