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Clarifying the interaction between cyclic oxime and acidic silanols in hierar...
Caprolactam (CL) is a high-value chemical and precursor to nylon-6. Industrially, a harsh, liquid acid catalyst transforms C6-oxime to CL but due to the risk and inefficiency of... -
An abiotic analogue of methane monooxygenase for the catalytic oxidation of h...
We propose to use INS to characterise the structural and vibrational properties of a new class of Fenton-like Fe(IV)O intermediates of potential relevance in the conversion of... -
Investigating the diffusion of cyclic oximes in hierarchically-porous catalys...
Caprolactam (CL) is a high-value chemical precursor to nylon-6. On an industrial scale an aggressive liquid-acid catalyst is used to transform C6-oxime to CL. Due to... -
Characterisation of intermediates in the production of eta-caprolactam
The commercially important polymer Nylon 6 is manufactured by ring-opening polymerization of eta-caprolactam. Industrially, eta-caprolactam is made by the Beckmann rearrangement... -
Role of acidic silanols and Brønsted acid sites in hierarchically porous SAPO...
The commercially important polymer Nylon 6 is manufactured by ring-opening polymerization of eta-caprolactam. Industrially, eta-caprolactam is conventionally made by the...