Major ion patterns of the Wiesent River catchment (Germany) measured in 2010

DOI

Karst areas and their catchments pose a great challenge for protection because fast conduit flow results in low natural attenuation of anthropogenic contaminants. Studies of the hydrochemistry of karst sources and river solutes are an important tool for securing and managing water resources. A study of the geochemical downriver evolution of the Wiesent River and its tributaries, located in a typical karst terrain, revealed unexpected downstream decreases of nitrate with maximum mean values of 30 mg/L at the source to minimum values of 18 mg/L near the river mouth. This trend persisted over the length of the river even though increased agricultural activities are evident in the downstream section of the catchment. This pattern is caused by fertilizer inputs via diffusive and fast conduits flow from karst lithology in the upstream area that may have reached the river's source even from beyond the hydrological catchment boundaries. Further downstream, these influences became diluted by tributary inputs that drain subcatchments dominated by claystone and sandstone lithologies that increased potassium and sulphate concentrations. Our findings indicate that bedrock geology remains the dominant control on the major ion chemistry of the Wiesent River and that agricultural influences are strongest near the headwaters despite increased land use further downstream, due to long‐term storage and accumulation in karst aquifers. This feature may not be unique to the Wiesent River system, as carbonates cover significant portions of the Earth's surface and subsequent work in other river systems could establish whether such patterns are ubiquitous worldwide.

A study of the geochemical downriver evolution of the Wiesent River (Germany) and its tributaries were carried out with bi-monthly sampling campaigns covering the period from February 2010 to November 2010. A total of 64 sample from the Wiesent River main course and 35 samples from it's six tributaries were analyzed for field parameters (temperature, electric conductivity, pH, O2 saturation, total alkalinity), major cations (sodium, potassium, lithium, ammonium, calcium, magnesium), and major anions (fluoride, chloride, nitrate, nitrite, sulfate, phosphate).

Supplement to: van Geldern, Robert; Schulte, Peter; Mader, Michael; Baier, Alfons; Barth, Johannes A C; Juhlke, Tobias René; Lee, Kern Y (2018): Insights into agricultural influences and weathering processes from major ion patterns. Hydrological Processes, 32(7), 891-903

Identifier
DOI https://doi.org/10.1594/PANGAEA.885224
Related Identifier https://doi.org/10.1002/hyp.11461
Metadata Access https://ws.pangaea.de/oai/provider?verb=GetRecord&metadataPrefix=datacite4&identifier=oai:pangaea.de:doi:10.1594/PANGAEA.885224
Provenance
Creator van Geldern, Robert ORCID logo; Schulte, Peter; Mader, Michael ORCID logo; Baier, Alfons; Barth, Johannes A C ORCID logo; Juhlke, Tobias René; Lee, Kern Y
Publisher PANGAEA
Publication Year 2018
Rights Creative Commons Attribution 3.0 Unported; https://creativecommons.org/licenses/by/3.0/
OpenAccess true
Representation
Language English
Resource Type Supplementary Publication Series of Datasets; Collection
Format application/zip
Size 2 datasets
Discipline Earth System Research
Spatial Coverage (11.139W, 49.738S, 11.335E, 49.977N)
Temporal Coverage Begin 2010-02-19T00:00:00Z
Temporal Coverage End 2010-11-08T00:00:00Z